Have you spoken to the child's parents about this OP? I think that's the very first thing you should do because chances are if he's saying it to you, he's saying the same to them at home when he doesn't get his way.
Next I would say no, I didn't hurt you, . You hurt your friend when you threw the toy, now sit here and cool off.
If he continues to say it I'd simply ignore it and have a chat with the parents at pick up.
He's 2, tomorrow he'll be on to something else.

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